Name : Phosphorus Symbol : P Atomic # : 15 Atom weight: 30.9738 Melting P. : 44.1 Boiling P. : 280 Oxidation : +3, -3, +5 Pronounced : FOS-fer-es From : Greek phosphoros, "bringer of light" Identified : Hennig Brand in 1669 Appearance : The most common white form is a waxy, phosphorescent solid Note : This element is noted for its ability to grow in the dark [Properties] Phosphorus belongs to the nitrogen group, Group VA, on the periodic table of the elements. It is a nonmetal, or metalloid, having properties closer to those of Sulfur (S) and arsenic (As) than to silicon (Si) and nitrogen in the same portion of the table. Phosphorus has ten known allotropic forms. This is an unusually large number of allotropes for any element, but the picture can be greatly simplified by placing each of them into one of three general categories: white, red, and black phosphorus. White phorphorus is a white, waxy substance that usually takes on a slightly yellow tinge due to the presence of impurities. There are two major allotropic forms of white phosphorus. The alpha form has a subic crystalline structure and is stable down to -78 degrees where it turns into the beta form. The beta form is somewhat more dense and has a hexagonal crystalline structure. Red phosphorus is formed by exposing white phosphorus to sunlight or heating it at about 250 degrees. Black phosphorus is also produced by heating white phosphorus, but in the presence of a mercury catalyst and seed crystal of black phosphorus. White phosphorus is by far the most volatile and explosive of the three basic allotropic forms. It is also the msot useful in the production of other compounds of phosphorus. Red phosphorus is, itself, a fairly stable form, but the heat from the simple friction is enough to convert it to explosive white phosphorus. This feature is used to great advantage in the manufacture of safely matches. Black phosphorus is the least reaction and has the least commercial value.