Name : Arsenic Symbol : As Atomic # : 33 Atom weight: 74.9216 Melting P. : 817 Boiling P. : 613 Oxidation : +3, -3, +5 Pronounced : AR-s'n-ik From : Latin arsenicum, and Greek, arsenikon: both are names for a popular pigment, yellow orpiment Identified : Possibly by Albertus Magnus in 1250 A.D. Appearance : Steel gray, brittle semimetal Note : Popularly known for its highly poisonous compounds [Properties] Arsenic is a semimetal, or metalloid element. It isn't quite a metal such as aluminum or tin, and it isn't quite a nonmetal such as sulfur and bromine. It belongs to a fairly small group of semimetal that share the same general area on the periodic table of the elements. The principal allotrope of the arsenic is gray arsenic. This is characterized as a brittle, silvery-gray metal. Two other allotropes, yellow and black arsenic, are unstable crystalline substances that can be produced by first heating, then cooling, gray arsenic. Gray arsenic tends to sublimate rather than go through a molten state. Heating gray arsenic to its sublimation temperature, 613 degrees, causes it to generate an arsenic vapor. If you cool this vapor slowly, you will see the black form of arsenic condensing on the sample. As the sample continues to cool and passes through the 360 degrees mark, the blakc arsenic changes back to the gray form. Cooling gray arsenic rapidly from its sublimation temperature, however, causes yellow arsenic to condense on the sample. Unlike black arsenic, the yellow attotrope does not automatically return to the gray form upon further cooling. The yellow allotrope is stable with respect to changes in temperature but is sensitive to light. Light energy converts yellow arsenic to the stable gray form.